Induction of chirality in nematic phases

نویسنده

  • G. Chilaya
چکیده

2014 Some electrooptic and thermooptic effects of cholesteric phase are used in liquid crystal visualisation and display systems provided spiral pitch is equal to a visible wavelength or several micrometers. Liquid crystals with cholesteric properties were generally cholesteric esters. Unfortunately these materials are chemically nonstable. More stable nematic liquid crystals twisted by mixing with chiral materials or by adding assimetric side chain have also cholesteric phase. In this case spiral pitch depends on many factors. This report unites theoretically predicted temperature and concentration dependence of pitch and compares it with some original or known results. Revue Phys. Appl. 16 (1981) 193-208’ ’

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Confinement-Induced Liquid Crystalline Transitions and Chirality Inversion in Amyloid Fibril Cholesteric Tactoids

Chirality is ubiquitous in nature and plays crucial roles in biology, medicine, physics and materials science 1–5. Understanding and controlling chirality is therefore an important research challenge with broad implications in fundamental and applied sciences. Unlike other classes of chiral colloids, such as nanocellulose or filamentous viruses, amyloid fibrils form nematic phases but appear to...

متن کامل

Application of Δ- and Λ-Isomerism of Octahedral Metal Complexes for Inducing Chiral Nematic Phases

The Delta- and Lambda-isomerism of octahedral metal complexes is employed as a source of chirality for inducing chiral nematic phases. By applying a wide range of chiral metal complexes as a dopant, it has been found that tris(beta-diketonato)metal(III) complexes exhibit an extremely high value of helical twisting power. The mechanism of induction of the chiral nematic phase is postulated on th...

متن کامل

Helix inversion in the chiral nematic and isotropic phases of a liquid crystal

Measurements of the chirality (2 pi/pitch) in the chiral nematic phase and of a structural constant proportional to the chirality in the isotropic liquid for a system in which a helix inversion line crosses the chiral nematic to isotropic phase transition line are reported. While the chirality shows a strong temperature dependence in the chiral nematic phase, it loses all temperature dependence...

متن کامل

Entropy-driven formation of chiral nematic phases by computer simulations

Predicting the macroscopic chiral behaviour of liquid crystals from the microscopic chirality of the particles is highly non-trivial, even when the chiral interactions are purely entropic in nature. Here we introduce a novel chiral hard-particle model, namely particles with a twisted polyhedral shape and obtain a stable fully entropy-driven cholesteric phase by computer simulations. By slightly...

متن کامل

Low symmetry tetrahedral nematic liquid crystal phases: Ambidextrous chirality and ambidextrous helicity.

We discuss the symmetry properties as well as the dynamic behavior of various non-polar nematic liquid crystal phases with tetrahedral order. We concentrate on systems that show biaxial nematic order coexisting with octupolar (tetrahedral) order. Non-polar examples are phases with D2 and S4 symmetries, which can be characterized as biaxial nematics lacking inversion symmetry. It is this combina...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2017